Resumo
Foram feitos estudos comparativos entre quatro métodos para determinação de nitrato em amostras de águas naturais, colhidas em dez poços na cidade de São Paulo. Procurou-se destacar os problemas operacionais e os possíveis interferentes para cada método. Com base nos resultados obtidos, foi sugerido o método do ácido fcnoldissulfônico como o mais apropriado para o uso em análises de rotina de amostras de água.
Referências
1. AMERICAN PUBLIC HEALTH ASSOCIATION - Standard methods for the examination of water and wastewater. 16th ed. Washington, APHA, 1985. p. 391-404.
2. BARNES, H. - A modified 2:5-xylenol method for nitrate estimations. Analyst., 75:388-92, 1950.
3. BURDEN, E.H.W.J. - The toxicology of nitrates and nitrites with particular reference to the potability of water supplies. Analyst, 86:429-33, 1961.
4. HORA, F.B. & WEBBE, P.J. - A source of serious error in the determination of nitrates by the phenoldisulphonic acid method and its remedy. Analyst., 85:567-9, 1960.
5. HUNTER, H. & COMLY, Y.D. - Cyanosis in infants caused by nitrites in well water. J. amer. medo Assoe., 129: 112-6, 1945.
6. KHOL, D.H.; SHEARER, G.B. & COMMONER, B. - Fertilizer nitrogen: contribution to nitrate in surface water in a com belt watershed. Science., New Y., 174:1331-4, 1971.
7. MONTGOMERY, H.A.C. & DYMOCK, J.F. The rapid determination of nitrate in fresh and saline waters. Analyst., 87:374-8, 1962.
8. WELGHE, N. & CLAEYS, A. - Rapid spectro-photometric determination of nitrates in mineral waters with resorcionol. Analyst., 110:313-4, 1985.
9. WEST, P.W. & RAMACHANDRAN T.P. - Spectrophotometric determination of nitrates using chromotropic acíd, Anal. Chim. Acta, 35:317-24, 1966.
10. WHO TASK GROUP ON ENVIRONMENTAL HEALTH CRITERIA FOR NITRATES, NITRITES AND N-NITROSO COMPOUNDS. Lyon, 1976. Nitrates, nitrites and N-nitroso compounds. Geneva, WHO, 1978. p. 17,31,32. (Environmental Health Criteria 5)
2. BARNES, H. - A modified 2:5-xylenol method for nitrate estimations. Analyst., 75:388-92, 1950.
3. BURDEN, E.H.W.J. - The toxicology of nitrates and nitrites with particular reference to the potability of water supplies. Analyst, 86:429-33, 1961.
4. HORA, F.B. & WEBBE, P.J. - A source of serious error in the determination of nitrates by the phenoldisulphonic acid method and its remedy. Analyst., 85:567-9, 1960.
5. HUNTER, H. & COMLY, Y.D. - Cyanosis in infants caused by nitrites in well water. J. amer. medo Assoe., 129: 112-6, 1945.
6. KHOL, D.H.; SHEARER, G.B. & COMMONER, B. - Fertilizer nitrogen: contribution to nitrate in surface water in a com belt watershed. Science., New Y., 174:1331-4, 1971.
7. MONTGOMERY, H.A.C. & DYMOCK, J.F. The rapid determination of nitrate in fresh and saline waters. Analyst., 87:374-8, 1962.
8. WELGHE, N. & CLAEYS, A. - Rapid spectro-photometric determination of nitrates in mineral waters with resorcionol. Analyst., 110:313-4, 1985.
9. WEST, P.W. & RAMACHANDRAN T.P. - Spectrophotometric determination of nitrates using chromotropic acíd, Anal. Chim. Acta, 35:317-24, 1966.
10. WHO TASK GROUP ON ENVIRONMENTAL HEALTH CRITERIA FOR NITRATES, NITRITES AND N-NITROSO COMPOUNDS. Lyon, 1976. Nitrates, nitrites and N-nitroso compounds. Geneva, WHO, 1978. p. 17,31,32. (Environmental Health Criteria 5)
Este trabalho está licenciado sob uma licença Creative Commons Attribution 4.0 International License.
Copyright (c) 1987 Jorge José do Vale Oliveira, Maria Isabel Vallilo, Nilva Aparecida R. Pedro, Odair Zenebon
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