Determination of mercury and methylmercury in fish and hair samples
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Keywords

methylmercury
fish
hair
cold vapor atomic absorption spectrometry

How to Cite

1.
Farias LA, Fávaro DIT, Vasconcellos MBA. Determination of mercury and methylmercury in fish and hair samples. Rev Inst Adolfo Lutz [Internet]. 2009 Aug. 1 [cited 2024 Jul. 22];68(3):451-60. Available from: https://periodicos.saude.sp.gov.br/RIAL/article/view/32707

Abstract

The cold vapor atomic absorption spectrometry (CVAAS) is one of the most useful analytical technique for mercury and methylmercury determinations in biological materials due to several advantagens such as operation facility, fast analytical response, good sensitivity and low cost. This study also shows the results obtained by our laboratory in the World-Wide Intercomparison Exercise for the Determination of Trace Elements and Methylmercury in Tuna Fish Flesh Homogenate (IAEA-436), during the period of October 2004 and July 2005. The precision and accuracy of the method for total mercury and MeHg determinations were verified by means of the reference material analyses. The results obtained showed good precision and accuracy with relative standard deviation ranged from 2.2 to 10 % and relative error from 0.4 to 12% for MeHg and relative standard deviation ranged from 2.6 to 11.7 % and relative error from 0.9 to 3.1% for Hg. The method presented has been shown to be suitable for determination of background levels of these contaminants in fish and hair samples and can be used in studies related to the health effects of mercury and its species in man.

https://doi.org/10.53393/rial.2009.v68.32707
PDF (Português (Brasil))

References

1. Mergler, D, Passos, C. Human mercury exposure and adverse health effects in the Amazon: a review. Cad. Saúde Pública 2008; 24 (4): 5503-20.

2. Hacon, S e col. An overview of mercury contamination research in the Amazon basin with an emphasis on Brazil. Cad. Saúde Pública 2008; 24 (7): 1479-92.

3. Farias, LA, Santos, NR, Favaro, DIT, Braga, ES. Mercúrio total em cabelo de crianças de uma população costeira, Cananeia, São Paulo, Brasil. Cad. Saúde Pública 2008, 24 (10):1-8.

4. Canela MC. Determinação de Mercúrio. Campinas: UNICAMP, 1995.

5. Goyer RA. Toxic effects of metals. In: Klaassen CD, Amdur MO, Doull J, eds. Casarett and Doull’s toxicology: the basic science of poisons. New York, NY: Macmillan Publishing In: Klaassen CD, Amdur MD, Doull J, eds. Casarett and Doull’s toxicology--the basic science of poisons. 3rd ed. New York, NY: Macmillan Publishing,1986.

6. Passos CJS., Mergler D, Lemire M, Fillion M, Guimarães JRD. Fish consumption and bioindicators of inorganic mercury exposure. The Science Total Environment 2003;373:68–76.

7. Virtanen JK, Rissanen TH, Voutilainen S, Tuomainen TP. Mercury as a risk factor for cardiovascular diseases. Journal of Nutritional Biochemistry 2007; 18:75-85.

8. Farias LA, Favaro DIT, Maihara VA, Vasconcellos MBA, Yuyama LK, Aguiar JPL, Alencar FJ. Assessment of daily dietary intake of Hg and some essential elements in diets of children from the Amazon region. Journal of Radioanalytical and Nuclear Chemistry 2006; 260 (2):383-7.

9. Quevauviller, P, Filippelli, M, Horvart, M. Method performance evaluation for methylmercury determination in fi sh and sediment. Trends in analytical chemistry 2000, 19:157-79.

10. Lai, R, HuanG, EL, Zhou, F, Wipf, DO. Selective Determination of Methylmercury by Flow-Injection Fast-Scan Voltammetry Selective Determination of Methylmercury by Flow- Injection Fast-Scan Voltammetry. Electroanalysis 1998, 10 (13):926-32.

11. Cappon, C J, Smith, JC. Breakdown of methylmercury in sodium hydroxide solution. Anal. Chem., 1980, 52:1527-9.

12. Ealy, JA, Shults,W D, Dean, J A. Extraction and Gas Cromatographic Determination of Methyl-, Ethyl-, and Methoxyethylmercury (II) Halides. Anal. Chem. Acta. 1973, 64: 235- 41.

13. Sanema AI., Haraguchi, K, Nagai, H. Preconcentration of inorganic mercury with an-exchange resin and direct reduction-aeration measurements by cold-vapour atomic absorption spectrometry. Anal. Chim. Acta, 1981, 130 (1):149-56.

14. Neagu, V., Cornelia, L., Simina, S., Untea, I.Unconventional ion exchange resins and their retention properties for Hg2+ ions. Reactive & Functional Polymers, 2007,67:1433–9.

15. Horvat, M, Byrne, AR. Preliminary study of the effects os some physical parameters on the stability methylmercury in biological samples. Analyst 1992, 117:665-8.

16. Westöö, G. Determination of methylmercury compounds in foodstuffs. I. methylmercury compounds in fi sh, identifi cation and determination. Acta Chem. Scand., 1966, 20 (8): 2131- 7.

17. Dan-YY., Hoang-YTT, Yu-Wei C, Nelson B. Improvements of reliability for methylmercury determination in environmental samples. Analytica Chimica Acta, 2009, 633:157-64.

18. Evans, O. & Mckee, GD. Determination of mercury (II) and organomercury compounds by reversed-phase liquid chromatography with reductive eletrochemical detection. Analyst., 1988, 113: 243-6.

19. Gibicar, D, Logar, M, Horvat, N, Marn-Pernat, A, Ponikvar, R.Horvat, M. Simultaneous determination of trace levels of ethylmercury and methylmercury in biological samples and vaccines using sodium tetra (n-propyl) borate as derivatizing agent. Anal. Bioanl. Chem., 2007, 388 (2):329-40.

20. Saouter, E. & Blattmann, B. Analyses of organic and inorganic mercury by atomic fl uorescence spectrometry using a semiautomatic analytical system. Anal. Chem., 1994, 66:2031-7.

21. Hatch, WR, Ott, WL. Determination of sub-microgram quantities of mercury by atomic absorption spectrophotometry. Anal. Chem., 1968, 40: 2085-7.

22. Poluektov, N. S.; Zelyukova, Y. V. Atomic absorption determination of mercury microcontaminations in alkali metal hydroxides (exchange of experience). Industrial Laboratory, 1969, 35 (2): 222-30.

23. Ribeiro, F, Neto, M.M.M, Rocha, M.M, Fonseca, IT.E. Voltammetric studies on the electrochemical determination of methylmercury in chloride medium at carbon microelectrodes. Analytica Chimica Acta, 2006, 579:227-34.

24. Mieczyslaw K, Iwona R. New methodology for anodic stripping voltammetric determination of methylmercury. Electrochemistry Communications, 2008, 10:1024-6.

25. Horvat, M. Mercury analysis and speciation. In Environmental Sample in Global and Regional Mercury Cycles: Sources, Fluxes and Mass Balances, p. 1-31, W. Baeyens et al (eds), 1996.

26. Deng, D-F; Teh, F-C; Teh, SJ. Effect of dietary methylmercury and seleno-methionine on Sacramento splittail larvae. Science of The Total Environment, 2008, 407:197-208.

27. Bisinoti, M. C.; Jardim, W.F.; Brito Junior, J. L.; Malm, O.; Guimarães, J. R. Um novo método para quantificar mercúrio orgânico (Hg orgânico) empregando a espectrometria de fl uorescência atômica

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