Evaluation of olive oil adulteration by physical and chemical parameters
pdf (Português (Brasil))

Keywords

Olive oil
Olive oil adulteration

How to Cite

1.
Aued-Pimentel S, Mancini-Filho J, Badolato ESG, Carvalho JB de. Evaluation of olive oil adulteration by physical and chemical parameters. Rev Inst Adolfo Lutz [Internet]. 1994 Dec. 30 [cited 2024 May 17];54(2):69-77. Available from: https://periodicos.saude.sp.gov.br/RIAL/article/view/35689

Abstract

In order to evaluate olive oil identity and quality characteristics fifteen analytical parameters from virgen olive oil and from its differents mixtures with soybean oil, were studied. The principal fatty acids composition, iodine value, refractive index, esqualene contents, especific extintions at 232 and 270 nm, acidity, peroxides index, the ratio of oleic to linoleic acids (O/Li) and a parameter from second derivative ultraviolet spectra (ΔK 1%/lcm 310 - 313 nm), were determined. The data were statistically treated by descriptive and principal component analysis techniques. Most of the parameters studied showed high correlation among them, as well as, a linear behaviour with adulteration level increase. The refrative index and linolenic acid contents showed to be the most sensitive parameters to discriminate olive oil adulteration with soybean oil, agreeing with the acceptable ranges given by Codex Alimentarius. Principal component analysis of parameters sets studied, were not more efficient than some individual parameters to evaluate adulteration. The evaluation of the ratio O/Li showed that this parameter can be utilized only as an indicator of olive oil adulteration, due to the variability of these fatty acids in vegetable oils.

https://doi.org/10.53393/rial.1994.54.35689
pdf (Português (Brasil))

References

1. APARICIO, R.; ALBI, T.; LANZON, A.; NAVAS, M.A. - SEXIA, um sistema experto para la identifícacion de aceites: base de datos de zonas olivareras. Grasas y aceites. Sevilla. 38(1):9-14. 1987.

2. APARICIO. R.; FERREIRO. L.; CERT. A.; LAZON. A.- Caracterización de aceites de oliva virgenes andaluces. Grasas y Aceites. Sevilla. 41(1): 23-39, 1990.

3. AUEO, S. - Adulteração de azeite de oliva. Bol. Inst. Adolfo Lutz, São Paulo. 1(1):8.1991.

4. AUEO-PIMENTEL. S.; ALMEIDA-GONÇALVES. M.I.; MANCINI-FILHO, J. - Aplicação da espectrofotometria derivada na avaliação da qualidade do azeite de oliva. Cienc. Tecnol. Aliment .. Campinas, 13(2):121-31, 1993.

5. BADOLATO, E.S.G.; DURANTE, F.; ALMEIDA, M.E.W.Z., SILVEIRA, N.V.V. - Óleo de oliva – avaliação de sua qualidade. Rev. Inst. Adolfo Lutz: São Paulo, 41(1):63-70,1981.

6. BANCO DO BRASIL. CACEX/DEPEC. Importação de mercadoria. País/porto. Jan./maio 1990 (ECI-780 - Microficha).

7. CALCULATEO iodine value. In: AMERICAN OIL CHEMISTS SOCIETY - Official methods and recommended practices of the American Oil Chemists
Society 4th ed. Champaign, IL, A.O.C.S., 1989. (Official Method Cd lc-85).

8. CHOUKROUN, M.; FAYE, O.; MARTEAU, M.; SOLERE, M.; SUORAUO, O.; SUORAUO, G.; VERETOUT, O. - Note sur la recherche de l'adulteration des huiles d' olive par les huiles de grignons d'olive. Rev. Fr. Corps. Gras. Paris, 31 (4/5): 191-3, 1994.

9. CODEX ALIMENTARIUS COMMISSION – Codex standards for edible fats and oils. Rome, FAO/ WHO, 1982 (CAC – vol 11).

10. CODEX ALIMENTARIUS COMMISSION – Codex standards for edible - fats and oils. Rome, FAO/ WHO, 1987. p. 46-75 (CAC - vol. 17).

11. CORDANI, LX & RIBEIRO-JR, RS. – Identificação das características de qualidade do óleo de oliva. São Paulo, IME-USP, 50p. 1990. (SEA. Relatório de análise Estatística 9001).

12. DUNTEMAN, G.H. - Principal component analysis. Beverly Hills, Sage Publications, 1989, 96 p.

13. EM SP azeite adulterado é apreendido - Folha de São Paulo, São Paulo, 30 Janeiro, 1981. p. 33.

14. FIRESTONE, O.; CARSON, K.L.; REINA, R.J. – Update on control of olive oil adulteration and misbranding in the United States. J. Am. Oil. Chem. Soc., Champaign, 65(5) 788-92.
15. FIRESTONE, O.; SUMMER, J.L.; REINA, RJ.; AOAMS, W.S. - Detection of adulterated and misbranded olive oil produts. J. Am. OU Chem. Soc.,Champaing,
62(11):1558-62, 1985.

16.GRACIAN, J. - The chemistry and analysis of olive oil. In: BOEKENOOGEN, H.A. Analysis and characterization of oils, fats and fat produts. London. Interciense Publ., 1986, v.2p.317-591.

17. GROB, K.; LANFRANCHI, M.; MARIANIN. C. – Evaluation of olive oils through the fatty alcohols, the sterols and their esters by coupled LC-CG. J. Am. Oil Chem. Soc., Champaing, 67(10):626-34, 1990.

18. INSTITUTO ADOLFO LUTZ (São Paulo) – Normas Analíticas do Instituto Adolfo Lutz. 3ª. ed. São Paulo, IMESP. 1985. v.l: métodos químicos e físicos para análise de alimentos, p. 245-66.

19. KAPOULAS, V.M. & ANDRIKOPOULOS, N.K. – Detection of olive oil adulteration with linoleic acidrich oils by reversed-phase high-performance liquid
chromatography. J. Chromatogr., Amsterdam, 366:311-20, 1986.

20. KAPOULAS, V.M. & ANDRIKOPOULOS, N.K. – Detection of virgin olive oil adulteration with refined oils by second-derivative spectrophotometry. Food Chem., Barking, 23:183-92, 1987.

21. KIRITSAKIS, A. & MARKAKIS, P. - Olive Oil: a review. Adv. Food Res., New York, 31:453-82, 1987.

22. LATTA, S. - Gourmet oils in the 1990s. INFORM, Champaign, 2(2):98-113, 1991.

23. MARTINEZ MORENO, J. - Tendances modernes des recherches sur l'huile d'olive dans le cadre de la recherché sur les coprs gras alimentaires. Hev. Pr.
Corps. Gras., Paris, 24(6):293-301, 1977.

24. SOARES, L.S. & AMAYA, D.R. - Identificação e quantificação de adulterantes em óleo de oliva por cromatografia gasosa. Bol. SBCTA, Campinas, 15 (1):1-17, 1981.

25. SZPIZ, RR.; PEREIRA, D.A.; JABLONKA, F.H. Avaliação de óleos comestíveis comercializados no Rio de Janeiro. Rio de Janeiro, EMBRAPA-CTAA, 1985. 11p (EMBRAPA-CTAA Boletim de Pesquisa, 13).

26. TISCORNIA, E.; FORINA, M.; EVANGELISTI - Composizione chimica dell'olio di oliva e sue variazone indotte dai processo di rattificazione. Riv. Ital. Sostanze Grasse, Milano, 59(9):519-59, 1982.

27. TSMIDIOU, M.; MACRAE, R; WILSON, I. – Authentication of virgen olive oils using principal component analysis of triglyceride and fatty acid profiles: Part I - Classification of greek olive oils. Food Chem., Barking, 25:227-39, 1987.

28. VAN NIEKERK, PJ. & BURGER, A.E.C. - The cstimation of the composition of edible oil mixtures. J. Am. Oil Chem. Soc., Champaign, 62(3) 531-8, 1985.

29. VIDAL, P.A.; RICCIARDI, AJ.; FERREIRA, J.F. - Determinação da adição de óleo de soja a outros óleos vegetais comestíveis por cromatografia em fase gasosa. Rev. Inst. Adolfo Lutz; São Paulo, 39(1): 67-77, 1979.
Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Copyright (c) 1994 Instituto Adolfo Lutz Journal

Downloads

Download data is not yet available.